What do you like about his films?
His movies have interesting visuals, if sometimes not totally consistent. His movies are generally more mood-pieces than they are plot-heavy, which I find very few directors to be good at. I'd recommend Chungking Express before you watch anything else, though. It's probably his most accessible.
This is a stellar set of DVDs 
I would be grabbing a few of them myself if not for double dipping. Is there anything on Labyrinth, Hard Boiled, or Taxi Driver that make it worthwhile?
IIRC (I only rented it), the previous release of Labyrinth was a one disc, barebones catalog deal, whereas this one is 2 discs and all. Fact is, I don't really care about the special features for something like Labyrinth. Hard-Boiled, well, this is the first DVD release of it since the Criterion, right? Or was there another one? It's a new transfer anyway (even if there are apparently some issues with it). Taxi Driver, the previous version was the same as the deluxe VHS version, with few special features, whereas this is a new transfer and it has a ton of new features.
Woah, Distantmantra, how common is that set? I can still get that, I only have one of the movies in it.