I picked up Sid Meier's Civilization Chronicles at work for $39 (not including my employee discount) which includes:
Every Version of Civilization: The set includes: Sid Meier's Civilization I, Sid Meier's Civilization II, Civilization II: Fantastic Worlds, Civilization II: Conflicts in Civilization, Civilization II: Test of Time, Sid Meier's Civilization III, Sid Meier's Civilization III: Play the World, Sid Meier's Civilization III: Conquests and Sid Meier's Civilization IV.
Civilization: The Card Game: An original tabletop card game designed by Civilization IV lead designer Soren Johnson, featuring more than 250 custom cards and rules based on Civilization IV.
The Chronicles of Civilization: A 96-page book containing the history of Civilization, as told through interviews with past Civilization designers, an interview with Sid Meier and lead designer Soren Johnson, an article by journalist and author Steven L. Kent on the significance of the series in the computer gaming industry, and other original literature.
Video DVD: DVD content includes a detailed presentation by lead designer Soren Johnson and artist Dorian Newcomb about the creation of Civilization IV, complemented by gameplay footage of every iteration of the game, game trailers from the Civilization series and more.